To answer this specific question, yes, if you have two windows accounts and
a version of Outlook that supports corp or imo mode, each account will use
the same Outlook mode.

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Diane Poremsky [MVP - Outlook]
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wrote in message
...
I have two users on my computer. If I change one user account to
corporate/workgroup mode, does it also change the other user to the
same? I would like to have POP3 for one userand corporate/workgroup
for another.

Please advise and thank you.