See if the information on the following page helps:

http://www.slipstick.com/mail1/sendaccount.htm

--
Jocelyn Fiorello
MVP - Outlook

*** Messages sent to my e-mail address will NOT be answered -- please reply
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"user" wrote:

I have XP station, with Outlook 2000 installed configured for a corporate
workgroup environment.
I have multiple internet e-mail accounts configured on the Outlook client

How do I set the account from which mail will be sent from?
It seems to default to in alphabetical order.
I have removed all account recreated the accounts under the one I wish to
send from, that didn’t fix the problem.